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The Oxidation-Reduction Potential of the System of Mn(II)EDTA-Mn(III)EDTA Complexes and the Stability Constant of Mn(III)EDTA Complex

  • Tanaka N
  • Shirakashi T
  • Ogino H
Bulletin of the Chemical Society of Japan (1965) 38(9) 1515-1517
DOI: 10.1246/bcsj.38.1515
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Abstract

The standard oxidation-reduction potential of the system of Mn(II)EDTA-Mn(III)EDTA complexes has been determined to be E°MnY=0.579V. vs. SCE from the potentiometric measurement with the rotated platinum electrode. From this value the logarithmic stability constant of the Mn(III)EDTA complex (logKMn(III)Y) has been calculated to be 24.9 at 25.0°C and μ=0.2.

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Tanaka, N., Shirakashi, T., & Ogino, H. (1965). The Oxidation-Reduction Potential of the System of Mn(II)EDTA-Mn(III)EDTA Complexes and the Stability Constant of Mn(III)EDTA Complex. Bulletin of the Chemical Society of Japan, 38(9), 1515–1517. https://doi.org/10.1246/bcsj.38.1515

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