S-ethyl N-benzoyldithiocarbamate: Two independent hydrogen-bonded R 22(8) dimers of different symmetry linked into chains by a C-H⋯π(arene) interaction

Abstract

The title compound, C10H11NOS2, crystallizes with Z′ = 2 in space group C2/c. The molecules are linked by two N-H⋯S hydrogen bonds [H⋯S = 2.60 and 2.62 Å, N⋯S = 3.350 (2) and 3.490 (2) Å, and N-H⋯S = 143 and 172°] into two distinct types of R22(8) dimer, viz. one generated by inversion and the other by a twofold rotation axis. A single C-H⋯π(arene) hydrogen bond links the two types of dimer into chains.