S-ethyl N-benzoyldithiocarbamate: Two independent hydrogen-bonded R 22(8) dimers of different symmetry linked into chains by a C-H⋯π(arene) interaction

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Abstract

The title compound, C10H11NOS2, crystallizes with Z′ = 2 in space group C2/c. The molecules are linked by two N-H⋯S hydrogen bonds [H⋯S = 2.60 and 2.62 Å, N⋯S = 3.350 (2) and 3.490 (2) Å, and N-H⋯S = 143 and 172°] into two distinct types of R22(8) dimer, viz. one generated by inversion and the other by a twofold rotation axis. A single C-H⋯π(arene) hydrogen bond links the two types of dimer into chains.

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Low, J. N., Cobo, J., Insuasty, H., Estrada, M., Cortés, E., & Glidewell, C. (2004). S-ethyl N-benzoyldithiocarbamate: Two independent hydrogen-bonded R 22(8) dimers of different symmetry linked into chains by a C-H⋯π(arene) interaction. Acta Crystallographica Section C: Crystal Structure Communications, 60(7). https://doi.org/10.1107/S0108270104012090

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