In Situ AFM Measurements of the Expansion and Contraction of Amorphous Sn-Co-C Films Reacting with Lithium

  • Lewis R
  • Timmons A
  • Mar R
  • et al.
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Abstract

In situ atomic force microscopy measurements of patterned amorphous Sn-Co-C sputtered films reacting with Li in an electrochemical cell have been made. Prismatic-shaped patches of Sn0.34 Co0.19 C0.47 were found to undergo reversible volume expansion of 175±5% [(Vfinal - Vinitial) Vinitial] without fracture. The a- Sn0.34 Co0.19 C0.47 was found to have a reversible specific capacity of 700±10 mAhg when cycled vs a Li metal negative electrode. © 2007 The Electrochemical Society.

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Lewis, R. B., Timmons, A., Mar, R. E., & Dahn, J. R. (2007). In Situ AFM Measurements of the Expansion and Contraction of Amorphous Sn-Co-C Films Reacting with Lithium. Journal of The Electrochemical Society, 154(3), A213. https://doi.org/10.1149/1.2429042

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