Observation of the dark state in ruthenium complexes using femtosecond infrared vibrational spectroscopy

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Abstract

Comprehensive analyses of the excited states of prototypical ruthenium complexes using time-resolved infrared vibrational spectroscopy reveal a peak that can be assigned to the dark 3MC (metal centered) state, which plays an important role for their photofunctions.

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Onda, K., Mukuta, T., Tanaka, S., Murata, K., & Inagaki, A. (2015). Observation of the dark state in ruthenium complexes using femtosecond infrared vibrational spectroscopy. In Springer Proceedings in Physics (Vol. 162, pp. 475–478). Springer Science and Business Media, LLC. https://doi.org/10.1007/978-3-319-13242-6_116

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