Carbon fiber and nickel coated carbon fiber-silica aerogel nanocomposite as low-frequency microwave absorbing materials

Abstract

Silica aerogel-based materials exhibit a great potential for application in many industrial applications due to their unique porous structure. In the framework of this study, carbon fiber and nickel coated carbon fiber-silica aerogel nanocomposites were proposed as effective electromagnetic shielding material. Herein, the initial oxidation of the surface of carbon fibers allowed the deposition of a durable Ni metallic nanolayer. The fibers prepared in this way were then introduced into a silica aerogel structure, which resulted in obtaining two nanocomposites that differed in terms of fiber volume content (10% and 15%). In addition, analogous systems containing fibers without a metallic nanolayer were studied. The conducted research indicated that carbon fibers with a Ni nanolayer present in the silica aerogel structure negatively affected the structural properties of the composite, but were characterized by two-times higher electrical conductivity of the composite. This was because the nickel nanolayer effectively blocked the binding of the fiber surface to the silica skeleton, which resulted in an increase of the density of the composite and a reduction in the specific surface area. The thermal stability of the material also deteriorated. Nevertheless, a very high electromagnetic radiation absorption capacity between 40 and 56 dB in the frequency range from 8 to 18 GHz was obtained.