This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. It summarizes the various approaches to the synthesis of tertiary xanthates then describes the intra- and intermolecular radical additions and combinations thereof that have so far been used to construct quaternary centers.
CITATION STYLE
Quiclet-Sire, B., & Zard, S. Z. (2019, November 1). The xanthate route to all-carbon quaternary centers. Science China Chemistry. Science in China Press. https://doi.org/10.1007/s11426-019-9587-x
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