A Simple Supramolecular Approach to Recycling Rare Earth Elements

Abstract

The rapid increase in demand for rare-earth elements reflects their crucial roles in climate critical technologies. However, the lack of simple solutions for the separation of these metals from waste materials and ores represents a significant barrier to sustainable and environmentally benign rare-earth production. We report the application of a supramolecular approach to this challenge, using a triamido-arene receptor to selectively precipitate f-elements through their encapsulation as hexanitratometalates. Single-step, near quantitative recovery of Nd/Pr directly from magnet scrap was observed without the need for pH adjustment or pretreatment of the acidic leach solution. The rare-earth nitrate was rapidly stripped from the host-guest precipitate with water and the receptor recycled for further use. Near quantitative and highly selective uptake of La-Nd and Th from lateritic rare-earth ores was also achieved with no uptake of any non-f-element. These results show that targeting f-element metalates in separations chemistry can deliver exceptional and unique selectivity that may have significant consequences in the sustainable production of the rare-earth elements.