Evaluation of Eulychnia acida phil. (cactaceae) extracts as corrosion inhibitors for carbon steel in acidic media.

Abstract

The process of pickling to remove corrosion products in metal pipes requires the use of an acidic solution together with corrosion inhibitors to protect the metal. However, the use of synthetic/commercial inhibitors has caused environmental pollution and human health problems. As a result, studies have begun to analyse natural extracts from several different plants as potential corrosion inhibitors, as they are generally more innocuous and/or biodegradable. The present study evaluates the effectiveness of aqueous extracts obtained from Eulychnia acida Phil. (Cactaceae) as potential corrosion inhibitors for carbon steel in acidic media. The total phenolic compound and flavonoid content of the aqueous extracts of the cactus species was determined prior to the experiments. The inhibition efficiency of the extracts obtained by decoction of the external bark, internal bark and medulla of the cactus stems were evaluated by mass loss, demonstrating an efficiency of 90% at concentrations of 100 and 1000 ppm. The polarization curve tests indicate an efficiency of over 80% inhibition at concentrations of 1000 and 1500 ppm. The results show that metabolites present in the extracts act as corrosion inhibitors and are able to promote surface protection by blocking active sites on the metal.