Abstract
A tetracarboxylic acid with a methyl-substituted siloxane core (L-H4) has been prepared and applied in the construction of water stable MOFs with low water affinity. L-H4 itself crystallizes as an interpenetrated 3D hydrogen-bonded network. Reaction of L-H4 with ZrIV/HfIV gave IMP-32-Zr/Hf-both 3D MOFs of scu topology.
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CITATION STYLE
APA
Delmas, L. C., White, A. J. P., Pugh, D., Evans, A., Isbell, M. A., Heng, J. Y. Y., … Davies, R. P. (2020). Stable metal-organic frameworks with low water affinity built from methyl-siloxane linkers. Chemical Communications, 56(57), 7905–7908. https://doi.org/10.1039/d0cc01186j
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