Valorization of lignin into aromatics has driven researchers for decades. In this research, niobium was deposited on oyster shells (OSNC) and carbon rods (CRNC) and tested as a catalyst for depolymerization of lignin. Catalysts (2%, 5%, and 8% loading) were synthesized via wet impregnation. Batch experiments were performed at 95◦ C, using 8 g of lignin, and 1 g of catalyst. Our research indicates that niobium supported catalysts are effective in partial oxidation of lignin. Maximum vanillin concentration for OSNC was found to be 86.25 mg L−1 (0.1 wt%) at 5% niobium whereas, as for CRNC, maximum vanillin concentration was found to be 139.40 mg L−1 (0.17 wt%) at 2% niobium loading. Addition of hydrogen peroxide into the batch reactor decreased the concentration of vanillin production.
CITATION STYLE
Das, L., Kolar, P., Sharma-Shivappa, R., Classen, J. J., & Osborne, J. A. (2017, December 1). Oxidative depolymerization of lignin using supported niobium catalysts. ChemEngineering. MDPI AG. https://doi.org/10.3390/chemengineering1020017
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