Preferential dissolution of benthic foraminiferal calcite during laboratory reductive cleaning

Abstract

We have investigated the effect of cleaning procedures on eight element/Ca ratios in three widely used benthic foraminifera species from core top and down core sediments. Two cleaning techniques were employed: (1) comparison between "Mg-cleaning" and "Cd-cleaning" methods and (2) comparison between the various constituent reagents. Li/Ca, B/Ca, and Sr/Ca ratios remained unchanged for samples subjected to different treatments, but Mg/Ca, Mn/Ca, Zn/Ca, Cd/Ca, and U/Ca were substantially decreased when foraminifera shells were cleaned with reagents containing citrate. In contrast, no significant decreases in element/Ca ratios were observed for samples cleaned in N 2H4 without citrate, indicating that the role of N2H4 was insignificant during reductive cleaning and that citrate is responsible for decreases of Mg/Ca, Mn/Ca, Zn/Ca, Cd/Ca, and U/Ca. Decreases in these ratios are most likely due to (1) removal of contaminant particles enriched in Mg, Mn, Zn, Cd and U and/or (2) preferential leaching of CaCO3 by the formation of stable metal complexes through chelation between citrate and metals heterogeneously distributed in foraminiferal shells. Due to the negligible effect of N2H4 and preferential dissolution of CaCO3 during reductive cleaning, it is suggested that the reductive cleaning step should be omitted and the "Mg-cleaning" method [Barker et al., 2003] could be employed to clean foraminiferal shells for trace element measurements. Copyright 2007 by the American Geophysical Union.