Femtosecond laser-driven shock synthesis of hexagonal diamond from highly oriented pyrolytic graphite

Abstract

We synthesized hexagonal diamond directly from highly oriented pyrolytic graphite (HOPG) using a femtosecond laser pulse without catalyst. A femtosecond laser pulse with wavelength of 800 nm, pulse width of 130 fs, the intensity of 2×1015 W/cm2 was irradiated onto the HOPG surface in air. Crystalline structures of the fs laser-affected region in the HOPG were analyzed using grazing-incidence XRD method. We found that the hexagonal diamond which is the metastable high-pressure phase of carbon appeared in the HOPG which was irradiated by the femtosecond laser normal to the basal plane. We suggest that the femtosecond laser-driven shock wave induces the graphite - hexagonal diamond transformation and that the hexagonal diamond is synthesized due to the rapidly cooling in the shock heated region. © 2009 IOP Publishing Ltd.