Vibrational coherence reveals the role of dark multiexciton states in ultrafast singlet exciton fission

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Abstract

We use 2D electronic photon-echo spectroscopy to study ultrafast singlet exciton fission in pentacene. Our observations and analysis of vibronic coherences provide insight to the role played by dark multiexcitonic states in mediating fission.

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Bakulin, A. A., Morgan, S. E., Alster, J., Egorova, D., Chin, A., Zigmantas, D., & Rao, A. (2015). Vibrational coherence reveals the role of dark multiexciton states in ultrafast singlet exciton fission. In Springer Proceedings in Physics (Vol. 162, pp. 226–229). Springer Science and Business Media, LLC. https://doi.org/10.1007/978-3-319-13242-6_54

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