(Matrix presented) A variety of substituted azabicyclo[n.1.0]alkanes were synthesized by intramolecular titanium-mediated cyclopropanation of N-benzyl-N-(2-alkylalk-3-enyl)formamides and N-benzyl-N-alkadienylformamides. N-Benzylpyrroline upon treatment with Grignard reagents undergoes a titanium-mediated carbomagnesiation to yield N-benzyl-N-(2-alkylbut-3-enyl)amines.
CITATION STYLE
Tebben, G. D., Rauch, K., Stratmann, C., Williams, C. M., & De Meijere, A. (2003). Intramolecular titanium-mediated aminocyclopropanation of terminal alkenes: Easy access to various substituted azabicyclo[n.1.0]alkanes. Organic Letters, 5(4), 483–485. https://doi.org/10.1021/ol027352q
Mendeley helps you to discover research relevant for your work.