Abstract
A Cr(iv)η2-peroxo complex crystallizes from 33% aqueous H2O2. The complex is a likely intermediate in catalytic disproportionation of H2O2 proposed to occur through a single metal site mechanism in solution-and solid state.
Cite
CITATION STYLE
APA
De Sousa, D. P., Bigelow, J. O., Sundberg, J., Que, L., & McKenzie, C. J. (2015). Caught! Crystal trapping of a side-on peroxo bound to Cr(IV). Chemical Communications, 51(14), 2802–2805. https://doi.org/10.1039/c4cc08785b
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