Methyl β-D-xylopyranoside was allowed to react with β-O-4-type quinone methide without a catalyst to elucidate the reactivities of secondary hydroxyl groups at the C2, C3, and C4 positions. Benzyl ether-type lignin-carbohydrate complex (LCC) compounds linked at the C2 and C4 positions were predominant, at a ratio of 2:3. However, the reactivity of the hydroxyl group at the C3 position was quite low. These results strongly suggest that the reactivity of the C2 hydroxyl group in xylan toward quinone methide intermediate is higher than that of the C3 hydroxyl group during biosynthesis of LCCs.
CITATION STYLE
Kishimoto, T., Ikeda, T., Karlsson, O., Magara, K., & Hosoya, S. (2002). Reactivity of secondary hydroxyl groups in methyl β-D-xylopyranoside toward a β-O-4-type quinone methide. Journal of Wood Science, 48(1), 32–37. https://doi.org/10.1007/BF00766235
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