Side-on coordinated distannene: An unprecedented nickel(0) complex

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Abstract

η2-coordination of a Sn-Sn bond: An intramolecular distannene was synthesized in a straightforward fashion from 4,5-dilithio-9,9-dimethylxanthene. This compound reacts with [Ni(cod) 2] to form a Ni0 complex with an unprecedented Sn 2Ni triangle (see scheme; cod=1,5-cyclooctadiene). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Henning, J., & Wesemann, L. (2012). Side-on coordinated distannene: An unprecedented nickel(0) complex. Angewandte Chemie - International Edition, 51(51), 12869–12873. https://doi.org/10.1002/anie.201206767

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