Carbon-coated Fe2O3 hollow sea urchin nanostructures as high-performance anode materials for lithium-ion battery

Abstract

Fe2O3 has become a promising anode material in lithium-ion batteries (LIBs) in light of its low cost, high theoretical capacity (1007 mA h g−1) and abundant reserves on the earth. Nevertheless, the practical application of Fe2O3 as the anode material in LIBs is greatly hindered by several severe issues, such as drastic capacity falloff, short cyclic life and huge volume change during the charge/discharge process. To tackle these limitations, carbon-coated Fe2O3 (Fe2O3@MOFC) composites with a hollow sea urchin nanostructure were prepared by an effective and controllable morphology-inherited strategy. Metal-organic framework (MOF)-coated FeOOH (FeOOH@-MIL-100(Fe)) was applied as the precursor and self-sacrificial template. During annealing, the outer MOF layer protected the structure of inner Fe2O3 from collapsing and converted to a carbon coating layer in situ. When applied as anode materials in LIBs, Fe2O3@MOFC composites showed an initial discharge capacity of 1366.9 mA h g−1 and a capacity preservation of 1551.3 mA h g−1 after 200 cycles at a current density of 0.1 A g−1. When increasing the current density to 1 A g−1, a reversible and high capacity of 1208.6 mA h g−1 was obtained. The enhanced electrochemical performance was attributed to the MOF-derived carbon coating layers and the unique hollow sea urchin nanostructures. They mitigated the effects of volume expansion, increased the lithium-ion mobility of electrode, and stabilized the as-formed solid electrolyte interphase films.