Polar or nonpolar? That is not the question for perovskite solar cells

Abstract

Perovskite solar cells (PSC) are promising next generation photovoltaic technologies, and there is considerable interest in the role of possible polarization of organic-inorganic halide perovskites (OIHPs) in photovoltaic conversion. The polarity of OIHPs is still hotly debated, however. In this review, we examine recent literature on the polarity of OIHPs from both theoretical and experimental points of view, and argue that they can be both polar and nonpolar, depending on composition, processing and environment. Implications of OIHP polarity to photovoltaic conversion are also discussed, and new insights gained through research efforts. In the future, integration of a local scanning probe with global macroscopic measurements in situ will provide invaluable microscopic insight into the intriguing macroscopic phenomena, while synchrotron diffractions and scanning transmission electron microscopy on more stable samples may ultimately settle the debate.