Synthesis of 2-(Trimethylsilyl)ethyl Benzenesulfenate and Benzeneselenenate and Their Reaction with Some Electrophiles in the Presence of Tetrabutylammonium Fluoride

  • Oida T
  • Ohnishi A
  • Shimamaki T
  • et al.
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Abstract

2-(Trimethylsilyl)ethyl benzenesulfenate was allowed to react with several halides in the presence of tetrabutylammonium fluoride (TBAF) to afford the corresponding phenyl sulfoxides as the main product. In the reaction of 2-(trimethylsilyl)ethyl benzeneselenenate and several halides with TBAF, the corresponding alcohols were obtained as the main product.

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Oida, T., Ohnishi, A., Shimamaki, T., Hayashi, Y., & Tanimoto, S. (1991). Synthesis of 2-(Trimethylsilyl)ethyl Benzenesulfenate and Benzeneselenenate and Their Reaction with Some Electrophiles in the Presence of Tetrabutylammonium Fluoride. Bulletin of the Chemical Society of Japan, 64(2), 702–704. https://doi.org/10.1246/bcsj.64.702

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