Homodyne and heterodyne X-ray photon correlation spectroscopy: Latex particles and elastomers

Abstract

In a coherent X-ray small-angle experiment, heterodyning between the scattering amplitudes of two samples is obtained by stacking a static reference and a fluctuating sample. Results of homodyne and heterodyne measurements are compared in the case of 98 nm diameter latex particles in glycerol. The method is also used for the study of the slow relaxation process of carbon-black-filled ethylene-propylene elastomers corresponding to the relaxation of the carbon black skeleton after a 100% elongation. On the scale of the 10 μm coherent beam, heterodyning is used to separate fluctuations from long-term flowing of the sample. We show that this flow can be observed for about 10 h, with velocities of the order of nanometres per second. Random fluctuations are dominant in the speckle changes only for large q values (q > 2 × 10-2 Å-1) and after a long relaxation time. © International Union of Crystallography 2007.