Abstract
In this chapter we review distinct well-defined planar models to illustrate the unique chemical properties that can be realized by oxide nanostructuring in the form of continuous ultra-thin films, extended islands and/or supported nanoclusters. The highlighted systems include metastable PdO films for C–H bond activation, multifunctional catalytic sites at copper/cerium-oxide island interfaces for water-gas shift reactions, and (WO3)3 and (MoO3)3 nanoclusters with active dioxo, O=M=O, moieties for dehydration and partial oxidation of alcohols.
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CITATION STYLE
Asthagiri, A., Dixon, D. A., Dohnálek, Z., Kay, B. D., Rodriguez, J. A., Rousseau, R., … Weaver, J. F. (2016). Catalytic chemistry on oxide nanostructures. In Springer Series in Materials Science (Vol. 234, pp. 251–280). Springer Verlag. https://doi.org/10.1007/978-3-319-28332-6_9
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