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Determination of side products in the photocatalytic generation of hydrogen with copper photosensitizers by resonance Raman spectroelectrochemistry

RSC Advances (2016) 6(107) 105801-105805
DOI: 10.1039/c6ra21469j
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Abstract

A combination of UV-Vis and resonance Raman spectroscopy in conjunction with electrochemistry is employed to reveal the nature of a side product formed when using heteroleptic Cu(i)-photosensitizers [(P^P)Cu(N^N)]+ for photocatalytic hydrogen generation. It is shown that homoleptic [Cu(N^N)2]+ complexes are formed under oxidative conditions confirming a proposed deactivation pathway.

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CITATION STYLE

APA

Zhang, Y., Heberle, M., Wächtler, M., Karnahl, M., & Dietzek, B. (2016). Determination of side products in the photocatalytic generation of hydrogen with copper photosensitizers by resonance Raman spectroelectrochemistry. RSC Advances, 6(107), 105801–105805. https://doi.org/10.1039/c6ra21469j

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