Solvent Effects on the Structural and Optical Properties of MAPbI3 Perovskite Thin Film for Photovoltaic Active Layer

Abstract

Controlling the crystallinity, homogeneity, and surface morphology is an efficient method of enhancing the perovskite layer. These improvements contribute toward the optimization of perovskite film morphology for its use in high-performance photovoltaic applications. Here, different solvents will be used in order to process the perovskite precursor, to improve the interfacial contacts through generating a smooth film and uniform crystal domains with large grains. The effect that the solvent has on the optical and structural properties of spin-coated methyl ammonium lead iodide (MAPbI3) perovskite thin films prepared using a single-step method was systematically investigated. The spin-coating parameters and precursor concentrations of MAI and PbI2 were optimized to produce uniform thin films using the different solvents N, N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), and γ-butyrolactone (GBL). The effect that the solvent has on the morphology of the MAPbI3 films was examined to determine how the materials can be structurally altered to make them highly efficient for use in perovskite hybrid photovoltaic applications. Scanning electron microscopy (SEM) and X-ray diffractometry (XRD) results show that the synthesized MAPbI3 films prepared using DMSO, DMF, and GBL exhibit the best crystallinity and optical characteristics (photoluminescence (PL)), respectively, of the prepared films. The optical properties resulting from the noticeable improvement PL of the films can be clearly correlated with their crystallinity, depending on the solvents used in their preparation. The film prepared in DMSO shows the highest transmittance and the highest bandgap energy of the prepared films.