Electrochemical Impedance Spectroscopy and Its Applications

Abstract

Electrochemistry has become an important and recognized field for the future since many of its approaches contemplate the establishment of stable energy supplies and the minimization of our impact on the environment. In this regard, electrochemistry can face both objectives by studying the electrode/solution interface. As a result, different electrochemical techniques can be used to study the interface to understand the electron transfer phenomena in different reactions. Considering this, one of the most useful techniques to understand the electrode/solution interface is electrochemical impedance spectroscopy. This technique allows us to describe the electrode behavior in the presence of a certain electrolyte in terms of electrical parameters such as resistances and capacitances, among others. With this information, we can infer the electrochemical behavior toward a specific reaction and the capacity of the electrode to carry on the electron transfer depending on its resistance (impedance) values. The aim of this chapter is to go from the theory, based on Ohm’s Law and its derivations, to actual applications. This will lead us to characterize the solution, electrode, and the interface between these two phases based on their electrical components by using an equivalent electrical circuit, such as the Randles equivalent circuit.