Waste glass as binder in alkali activated slag–fly ash mortars

Abstract

This paper illustrates the application of waste glass powder as part of the binder in slag–fly ash systems activated by NaOH and NaOH/Na2CO3 activators. To evaluate the reaction kinetics, reaction products, mechanical properties, and durability performance of glass powder modified alkali activated slag–fly ash systems, calorimetry test, X-ray diffraction, FTIR, strength test, drying shrinkage tests, and carbonation test were conducted. From the isothermal calorimeter results, glass powder shows a higher reactivity compared to fly ash but still lower than slag. The reaction products of glass power modified samples exhibit an enhancement of polymerization degree of Si–O–T, observed in FTIR. As a consequence, higher drying shrinkage exists in glass modified mortars. The mechanical performance of different samples is mostly controlled by the Ca/Si of dry mixtures and activator type. After the slag–fly ash binder system was modified by the waste glass, a significant enhancement of resistance to carbonation was identified, especially for NaOH/Na2CO3 activated mortars, which show an increase of 300% on the carbonation resistance ability compared to the reference sample. The Na/(Si + Al) ratio of dry mixtures exhibits a positive correlation with carbonation resistance.