Variational calculation of the tunneling system interacting with a heat bath. II. Dynamics of an asymmetric tunneling system

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Abstract

The dynamics of tunneling of an asymmetric double well interacting with a heat bath is reexamined in the binary collision dilute gas phase limit and investigated in the harmonic bath case. (a) In both cases dynamic and static asymmetries are additive. (b) In both cases, when the tunneling amplitude is not renormalized to a value of zero, the effect of asymmetry on the approach to equilibrium due to incoherent tunneling only quantitatively differs from the symmetric double well. (c) When the renormalized tunneling amplitude is zero, the asymmetric tunneling turns dephasing into population relaxation, (d) Variational methods again give results in agreement with renormalization group and instanton calculations. © 1985 American Institute of Physics.

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Harris, R. A., & Silbey, R. (1985). Variational calculation of the tunneling system interacting with a heat bath. II. Dynamics of an asymmetric tunneling system. The Journal of Chemical Physics, 83(3), 1069–1074. https://doi.org/10.1063/1.449469

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