The kinetics and mechanism of the photoinduced reaction of water oxidation with potassium persulfate in the presence of the tris(bipyridyl) complex bpy3RuCl2 ∙ 6H2O as a photosensitizer and the trinuclear ruthenium complex (NH3)5Ru–O–Ru(NH3)4–O–Ru(NH3)5Cl6 have been studied. It has been shown that this complex is converted to a more active water oxidation catalyst when four or five NH3 ligands are replaced by oxygen atoms.
CITATION STYLE
Dzhabiev, T. S., Dzhabieva, Z. M., Dobrygin, V. V., Kabachkov, E. N., & Tkachenko, L. I. (2018). Photoinduced Oxidation of Water with Potassium Persulfate in the Presence of Ruthenium Trinuclear Complex. High Energy Chemistry, 52(5), 373–377. https://doi.org/10.1134/S0018143918050065
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