It is well known that the system NaF-AlF3, which constitutes the “backbone” of the electrolyte used in primary aluminium manufacture, forms Na+, F-, and a number of fluoro-aluminate anion complexes in the molten state. Since mainly the Na+ ion carries electric current, the aluminium-containing complexes must diffuse towards the cathode, resulting in concentration gradients in the cathode boundary layer. Starting from a structural model for the melt containing five anion species, it was possible to calculate the concentration gradients of the individual ions using the Stefan-Maxwell equation for diffusion in a multi-component system. Generally, AlF4- and Al2F7- were transported towards the cathode, while F- and AlF63- moved away from the cathode. For NaF/AlF3 molar ratios higher than 2.0, AlF52- moved towards the cathode, while it diffused away from the cathode in more acid melts.
CITATION STYLE
Solheim, A. (2016). Concentration gradients of individual anion species in the cathode boundary layer of aluminium reduction cells. In Light Metals 2012 (pp. 665–670). Springer International Publishing. https://doi.org/10.1007/978-3-319-48179-1_114
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