Ultrasound-induced gelation of a giant macrocycle

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Abstract

A 68-membered macrocycle undergoes ultrasound-induced supramolecular gelation in acetonitrile. The sonogel shows a remarkable thermostability, indicating that self-assembly is mediated by exceptionally robust non-covalent interactions. Model compounds indicate that the macrocyclic topology is essential for gelation to occur.

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Núñez-Villanueva, D., Jinks, M. A., Gómez Magenti, J., & Hunter, C. A. (2018). Ultrasound-induced gelation of a giant macrocycle. Chemical Communications, 54(77), 10874–10877. https://doi.org/10.1039/c8cc04742a

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