1-Benzoyl-3,3-bis(propan-2-yl)thiourea

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Abstract

Two independent thiourea derivatives comprise the asymmetric unit of the title compound, C14H20N2OS. The major difference between the mol-ecules relates to a twist in the relative orientation of the benzene rings [torsion angles = 4.5 (2) and -19.9 (2)° for the two independent mol-ecules]. The thio-carbonyl and carbonyl groups lie to opposite sides of the mol-ecule as there are twists about the central N - S bond [torsion angles = 83.90 (15) and 81.77 (15)°]. Supra-molecular chains extending parallel to [101] with a stepped topology and mediated by N - H⋯O hydrogen bonding feature in the crystal structure. C - H⋯O and C - H⋯π inter-actions are also present.

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Gunasekaran, N., Karvembu, R., Ng, S. W., & Tiekink, E. R. T. (2010). 1-Benzoyl-3,3-bis(propan-2-yl)thiourea. Acta Crystallographica Section E: Structure Reports Online, 66(8). https://doi.org/10.1107/S1600536810028862

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