The Dynamics of Aqueous Hydroxide Ion Transport Probed via Ultrafast Vibrational Echo Experiments

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Abstract

We use peakshift, transient grating, and 2D IR measurements to probe the dynamics of NaOD solutions. Our experiments suggest that OD- possesses a stable solvation shell and signatures of fast intermolecular proton transfer are observed.

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Roberts, S. T., Petersen, P. B., Ramashesha, K., & Tokmakoff, A. (2009). The Dynamics of Aqueous Hydroxide Ion Transport Probed via Ultrafast Vibrational Echo Experiments. In Springer Series in Chemical Physics (Vol. 92, pp. 481–483). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-540-95946-5_156

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