Abstract
Room to swing a cat: A chiral disulfonimide has been designed as a powerful new motif for asymmetric catalysis. As a first illustration, a highly efficient and enantioselective Mukaiyama aldol reaction has been developed (see scheme). The actual catalyst is proposed to be an N-silyl imide which is generated in situ. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
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Garcia-Garcia, P., Lay, F., Garcia-Garcia, P., Rabalakos, C., & List, B. (2009). A powerful chiral counteranion motif for asymmetric catalysis. Angewandte Chemie - International Edition, 48(24), 4363–4366. https://doi.org/10.1002/anie.200901768
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