Aurophilicity under pressure: A combined crystallographic and: In situ spectroscopic study

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Abstract

High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(i) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.

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O’Connor, A. E., Mirzadeh, N., Bhargava, S. K., Easun, T. L., Schröder, M., & Blake, A. J. (2016). Aurophilicity under pressure: A combined crystallographic and: In situ spectroscopic study. Chemical Communications, 52(41), 6769–6772. https://doi.org/10.1039/c6cc00923a

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