N-hydroxyphthalimide on a polystyrene support coated with Co(II)-containing ionic liquid as a new catalytic system for solvent-free ethylbenzene oxidation

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Abstract

The oxidation of ethylbenzene using dioxygen was carried out applying a new catalytic system—heterogeneous N-hydroxyphthalimide (PS-NHPI) coated with an ionic liquid containing CoCl2 . The catalytic system represents a combination of solid catalyst with ionic liquid layer (SCILL) and supported ionic liquid phase (SILP) techniques, wherein the resulting system utilizes CoCl2 dissolved in the 1-ethyl-3-methylimidazolium octyl sulphate ([emim)][OcOSO3 ]) ionic liquid phase that is layered onto the solid catalyst support. PS-NHPI was obtained by immobilizing N-hydroxyphthalimide on chloromethyl polystyrene resins by ester bonds. It was observed that novel SCILL/SILP systems significantly improved the selectivity toward acetophenone. We also demonstrate that these systems can be separated from the reaction mixture and recycled without appreciably reducing its activity and selectivity.

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Talik, G., Osial, A., Grymel, M., & Orlińska, B. (2020). N-hydroxyphthalimide on a polystyrene support coated with Co(II)-containing ionic liquid as a new catalytic system for solvent-free ethylbenzene oxidation. Catalysts, 10(12), 1–19. https://doi.org/10.3390/catal10121367

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