Construction of a TTT–η diagram of high–refractive polyurethane based on curing kinetics

Abstract

A time–temperature–transformation–viscosity (TTT–η) diagram can reflect changes in the physical states of a resin, which take on significance for the study of the curing process of polyure-thane resin lenses. Coupling the differential scanning calorimetry (DSC) test, the curing kinetic parameters of 1,4–bis(isocyanatomethyl)cyclohexane (H6XDI)/2,3–bis((2–mercaptoethyl)thio)–1–pro-panethiol (BES) polyurethane system were obtained. By phenomenological modeling, the relationships between degree, temperature, and time were obtained. An isothermal DSC test was carried out at 423 K. Based on the DiBenedetto equation, the relationships between glass transition temperature, degree of cure, and time were obtained, and the glass transition temperature was thus correlated with temperature and time. The gelation time at different temperatures was measured by rotary rheometry, and the relationship between gelation time and gelation temperature was established. The time–temperature–transformation (TTT) diagram of H6XDI/BES system was constructed accordingly. Subsequently, a six–parameter double Arrhenius equation was used as the basis for the rheological study. The viscosity was examined during the curing process. The TTT–η diagram was obtained, which laid the theoretical foundation for the optimization and setting of processing parameters.