We have investigated the optical response of Ni(dmg)2 thin film by pump-probe spectroscopy under excitation of the metal-to-ligand charge transfer(MLCT) absorption band. Almost the same photo-induced spectral change was observed as in the case of the resonant excitation to 1-D exciton absorption in Pt(dmg)2. It rises up within 200fs. This shows that the MLCT 'molecular ' excited state relaxes to 1-D intermolecular exciton state in such a short time.
CITATION STYLE
Iwai, S., Kamata, T., Yamamoto, K., Ohta, T., Fukaya, T., & Murata, S. (1998). UItrafast relaxation processes of Metal-to-Ligand Charge Transfer excited state in one-dimensional metal complex. Springer Series in Chemical Physics, 63, 502–504. https://doi.org/10.1007/978-3-642-72289-9_150
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