Abstract
Angular furanocoumarins (1) were synthesized via sequential reactions of vinylation of halo-hydroxycoumarins (5 or 6) with chlorodimethylvinylsilane (8) and Pd catalyst, oxidation of Tl(NO3)3 in methanol, and treatment with acid.
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Harayama, T., & Nishita, Y. (1996). Efficient and convenient synthesis of angular furanocoumarins from hydroxycoumarins. Chemical and Pharmaceutical Bulletin, 44(10), 1986–1988. https://doi.org/10.1248/cpb.44.1986
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