Ethyl 5-((1E)-1-{(E)-2-[1-(4-ethoxycarbonyl-3-methyl-1,2-oxazol-5-yl) ethylidene]hydrazin-1-ylidene}ethyl)-3-methyl-1,2-oxazole-4-carboxylate

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Abstract

The complete molecule of the title compound, C 18H 22N 4O 6, is generated by the application of a twofold axis of symmetry. Twists are evident in the molecule, i.e. between each - C=N - N group and the adjacent oxazole ring [dihedral angle = 46.08 (12) °] and between the latter and attached ester group [excluding the terminal methyl group; dihedral angle = 24.4 (7) °]. In the crystal, C - H⋯O and π-π [3.5990 (11) Å] contacts connect molecules into supramolecular arrays in the ac plane. These stack along the b axis, being connected by weak π-π [3.3903 (11) Å] interactions.

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Asiri, A. M., Al-Youbi, A. O., Faidallah, H. M., Ng, S. W., & Tiekink, E. R. T. (2011). Ethyl 5-((1E)-1-{(E)-2-[1-(4-ethoxycarbonyl-3-methyl-1,2-oxazol-5-yl) ethylidene]hydrazin-1-ylidene}ethyl)-3-methyl-1,2-oxazole-4-carboxylate. Acta Crystallographica Section E: Structure Reports Online, 67(9). https://doi.org/10.1107/S1600536811032004

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