Thermal and mechanical properties of chitosan/SiO2 hybrid composites

Abstract

Chitosan-silica (CSSi) hybrid films have been fabricated by sol-gel process using tetraethoxysilane (TEOS) as precursor. The structure of the resulting hybrid has been characterized by Fourier transform infrared spectroscopy (FTIR). Fracture surface has been revealed through a field emission-scanning electron microscopy/energy dispersive spectrometer (FE-SEM/EDS) to probe the dispersion degree and the size of SiO2 particle. Study of morphology using a SEM micrograph and the High Resolution Transmission Electron Microscopy (HRTEM) images of the nanocomposite films suggests that the SiO2 nanoparticles are within the range of 2-7nm in diameter and are uniformly dispersed in the polymer matrix. Thermal properties of these composite materials have been studied as a function of silica, indicating that thermal stability of the chitosan film is enhanced. Dynamical mechanical thermal analysis (DMTA) has been carried out to measure the shift in the glass transition temperature (Tg) of the composites from the maxima of the transition curves. The glass transition temperature and the storage modulus show an increase with increasing silica content. The maximum increase in the Tg value, that is, 159.37 °C, is seen with 30 wt silica. A gradual increase of 3.0GPa in the modulus relative to the pure polymer is observed. © 2010 F. Al-Sagheer and S. Muslim.