Efficient Removal of Methyl Orange from Wastewater by Polymeric Chitosan-iso-vanillin

Abstract

Methods: In this study, the removal of Methyl Orange (MO) dye from wastewater using a chitosan-iso-vanillin polymer was evaluated. The removal of MO from an aqueous solution was studied in a batch system, using the modified chitosan polymer. Results: The results indicate that the removal of MO by the modified chitosan was affected by the solution pH, sorbent dosage, initial MO concentration, contact time, and temperature. The experimental data were fitted to the Langmuir, Freundlich, and Temkin isotherms, and Freundlich isotherm showed the best fit. The kinetic data were fitted to the pseudo-first-order and pseudo-second-order rate equations. Thus, the removal of MO was controlled via chemisorption, and the removal rate was 97.9% after 3 h at an initial MO concentration of 100 ppm and a sorbent dose of 0.05 g. The adsorption behavior of the modified chitosan for the removal of MO was well-described using the pseudo-second-order kinetic model. Intraparticle diffusion analysis was also conducted, and the thermodynamic properties, including entropy (∆S), enthalpy (∆H), and free energy (∆G), were determined. Conclusion: The pH, initial MO concentration, sorbent dosage, adsorption temperature, and contact time had a significant effect on the adsorption of MO by chitosan-iso-vanillin.