Abstract
Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(Cy2PCH2CH2PCy2)(NBA)][BArF4]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.
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CITATION STYLE
Bukvic, A. J., Crivoi, D. G., Garwood, H. G., McKay, A. I., Chen, T. T. D., Martínez-Martínez, A. J., & Weller, A. S. (2020). Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer. Chemical Communications, 56(31), 4328–4331. https://doi.org/10.1039/d0cc01140a
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