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Boron-heck reaction of cyclic enaminones: Regioselective direct arylation via oxidative palladium(II) catalysis

Organic Letters (2014) 16(6) 1574-1577
DOI: 10.1021/ol500105d
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Abstract

An oxidative boron-Heck reaction of cyclic enaminones with arylboronic acids is reported. This protocol provides a regioselective arylation at the C6 position of cyclic enaminones. When an N-carbamylated cyclic enaminone was employed, a switch to a conjugate addition reaction occurred in the presence of acid. © 2014 American Chemical Society.

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Kim, Y. W., & Georg, G. I. (2014). Boron-heck reaction of cyclic enaminones: Regioselective direct arylation via oxidative palladium(II) catalysis. Organic Letters, 16(6), 1574–1577. https://doi.org/10.1021/ol500105d

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