Solid-state-trapped reactive ammonium carbamate self-derivative salts of prolinamide

Abstract

Trapped within: We report single-crystal characterization of polymorphs of the ammonium carbamate self-derivative salt of prolinamide, and the first crystal structure of prolinamide and of derived products. This study emphasizes the reactivity of carbonated amines in the solid state and opens perspectives for a systematic study of (solid-state) reactions involving these trapped reactive species. © 2013 The Authors. Published by Wiley-VCH Verlag GmbH& Co. KGaA, Weinheim.