Antisolvent sonocrystallisation of sodium chloride and the evaluation of the ultrasound energy using modified classical nucleation theory

Abstract

The crystal nucleation rate of sodium chloride in ethanol was investigated by measuring the induction time at various supersaturation ratios under silent and ultrasound irradiation at frequencies between 22 and 500 kHz. Under silent conditions, the data follows the classical nucleation theory showing both the homogeneous and heterogeneous regions and giving an interfacial surface tension of 31.0 mN m−2. Sonication led to a non-linearity in the data and was fitted by a modified classical nucleation theory to account for the additional free energy being supplemented by sonication. For 98 kHz, this free energy increased from 1.33 × 108 to 1.90 × 108 J m−3 for sonication powers of 2 to 15 W, respectively. It is speculated that the energy was supplemented by the localised bubble collapses and collisions. Increasing the frequency from 22 to 500 kHz revealed that a minimum induction time was obtained at frequencies between 44 and 98 kHz, which has been attributed to the overall collapse intensity being the strongest at these frequencies.