Dehydration of Methanol to Dimethyl Ether over ZSM-5 Zeolite

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Abstract

Methanol dehydration to dimethyl ether (DME) has been investigated over ZSM-5 zeolites and compared with that of γ-Al2O3. Although the catalytic activity was decreased with an increase in silica/ alumina ratio, the DME selectivity increased. H-ZSM-5 and NaH-ZSM-5 zeolites were more active for conversion of methanol to DME than γ-Al 2O3. Na+ ion-exchanged H-ZSM-5 (NaH-ZSM-5) shows higher DME selectivity than H-ZSM-5 due to the selective removal of strong acid sites.

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Jiang, S., Hwang, J. S., Jin, T., Cai, T., Cho, W., Baek, Y. S., & Park, S. E. (2004). Dehydration of Methanol to Dimethyl Ether over ZSM-5 Zeolite. Bulletin of the Korean Chemical Society, 25(2), 185–189. https://doi.org/10.5012/bkcs.2004.25.2.185

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