Synthesis and structure of single-crystal marcasite

  • Drabek M
  • Rieder M
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Abstract

Marcasite single crystals were synthesized directly by a reaction of aqueous solutions containing Fe2+ and Fe 3+ with H 2 S and polysulphides at 200°C. It might be that natural marcasite formed according to some similar recipe, making use of an interaction of H 2 S and polysulphides with pore fluids containing Fe 2+ or Fe 3+ e.g.. iron sulphates or chlorides. The structure of synthetic marcasite was refined from synchrotron diffraction data by the Rietveld method.

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Drabek, M., & Rieder, M. (2005). Synthesis and structure of single-crystal marcasite. In Mineral Deposit Research: Meeting the Global Challenge (pp. 111–113). Springer Berlin Heidelberg. https://doi.org/10.1007/3-540-27946-6_29

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