Evaluation of Levels of Selected Heavy Metals in Kales, Soils and Water Collected from Irrigated Farms along River Moiben, Uasin-Gishu County, Kenya

Abstract

There has been a rapidly increasing urbanization and industrialization as well as increased usage of agrochemicals in the recent few years which have resulted in accumulation of heavy metals in cultivated food, soils and water. This research aimed at establishing the levels of Zn2+, Cd2+, Cu2+, Cr2+, Mn2+, Fe2+ and Pb2+ metal ions in kales, soil and irrigation water on farms along river Moiben. Twenty seven samples of vegetables, soil and water samples were collected using purposive sampling method, that is, the samples were collected from the households who had kales in their farms. Samples were then dried, grounded, digested and analyzed using Inductive Couple Plasma-Optical Emission Spectroscopy (ICP-OES). The results showed that the Fe had the highest mean in soil and water with the values of 250.22 ± 85.37 and 0.72 ± 0.33 mg/kg respectively, while in kales Zn value was highest with a value of 0.0154 ± 0.007 mg/kg. The metal ion concentrations in the soils and the irrigation water were higher than in kales. The concentrations on the metal ions were following this order Fe > Mn > Zn > Cu > Cr > Pb > Cd for soil as well as for water but for the kales sample it followed slightly different order Zn > Fe > Mn > Cu > Cr > Pb > Cd. In soil samples, metal ions concentrations (mg/kg) were found to be high compared to the levels in water and kales. ANOVA tests revealed that the mean difference in heavy metals concentration from different stations within the area was insignificant (P > 0.05) with an exception of Cd (p = 0.001) in water samples, Fe (p = 0.007) in kales samples, Zn (p = 0.016) and Cd (p = 0.011) in the samples of soil. Results were compared to the acceptable levels set by World Health Organization (WHO) and the study showed that for kales, concentrations of the metal ions were all lower than the (WHO) set standards. For water samples, Fe, Pb, Mn metal ions were above the WHO set standards. The presence of the investigated heavy metals in the samples could be pointed to excessive use of agrochemicals as indicated by our earlier survey on the use of agrochemicals. We therefore recommend thorough investigations and monitoring of the said heavy metals in the commercially distributed agrochemicals.