Abstract
Described here is the radical-mediated hydrodifluoromethylation of alkenes that occurs under transition-metal-free conditions by using the phosphonium salt [Ph3P+CF2H]Br- under the irradiation of 26 W household compact fluorescent light. The reaction lends itself to a convenient protocol for the installation of a C-CF2H bond while maintaining good functional group tolerance.
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CITATION STYLE
APA
Yu, J., Lin, J. H., Cao, Y. C., & Xiao, J. C. (2019). Visible-light-induced radical hydrodifluoromethylation of alkenes. Organic Chemistry Frontiers, 6(20), 3580–3583. https://doi.org/10.1039/c9qo00919a
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