Polyimides: Synthesis, characterization and its application to CO 2 adsorption

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Abstract

Polyimides were synthesized using 3,3′,4,4′- biphenyltertracarboxylic dianhydride, (BPDA), tetraethylenepentamine (TEPA) and tris(2-aminoethyl)amine (TAEA) and tested for CO2 adsorption. They were characterized by FT-IR, TGA, DSC and BET techniques. The polyimides were thermally stable upto 400 °C. The polyimide, P2 with significant amount of TEPA and TAEA exhibited higher CO2 adsorption of about 6 wt% at 30 °C than others. The polyimide with only TEPA or TAEA exhibited lower CO 2 adsorption. Hence, presence of both the amines is important for high CO2 uptake. © 2012 Springer-Verlag Berlin Heidelberg.

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Hemalatha, P., Ganesh, M., Peng, M. M., Jong, E. M., Palanichamy, M., & Jang, H. T. (2012). Polyimides: Synthesis, characterization and its application to CO 2 adsorption. In Communications in Computer and Information Science (Vol. 341 CCIS, pp. 229–236). Springer Verlag. https://doi.org/10.1007/978-3-642-35248-5_32

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